Does the State's Popular vote ALWAYS reflect the State's electoral vote?

That is what I want to know. I understand if 1 person gets 51% of the NATIONS popular votes, and 2nd person gets 49% but more electoral votes then the 2nd person wins. But what I am asking is has a state's popular vote ever said VOTE one thing and It went the other way just because of the electoral college. If so when and Which state